Advances in Inorganic Chemistry: Inorganic Reaction by Colin D. Hubbard Rudi Van Eldik

By Colin D. Hubbard Rudi Van Eldik

The Advances in Inorganic Chemistry sequence offers well timed and informative summaries of the present growth in quite a few topic parts inside of inorganic chemistry starting from bio-inorganic to reliable nation reports. This acclaimed serial good points experiences written by means of specialists within the zone and is an imperative connection with complicated researchers. each one quantity of Advances in Inorganic Chemistry includes an index, and every bankruptcy is absolutely referenced. This, the 54th quantity within the sequence maintains this custom delivering complete experiences via prime specialists within the box with the focal point on inorganic and bioinorganic response mechanisms. * the newest quantity during this hugely winning sequence is devoted to inorganic and bioinorganic response mechanisms* entire reports written by way of prime specialists within the box

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FIG. 10. Possible mechanistic paths for water exchange on eight- and nine-coordinate lanthanides. predicted by this model: the a-activated mechanism for the small eightcoordinate ions, determined via the negative activation volumes, should be replaced by a d-activated mechanism for the larger nine-coordinate ions. This change in mechanism is supported by a computational study using classical molecular dynamics simulation. In recent years the subject of water exchange on lanthanide complexes attracted increasing attention owing to the use of Gd3+ as a contrast agent in medical magnetic resonance imaging (MRI).

E Studied in benzene diluent. f Sulfur bonded. g Oxygen bonded. h Studied in d3 -chloroform diluent. i Studied in d6 -acetone diluent. A. DUNAND et al. [Pt(H2O)4]2+ [Pt{C6H3(CH2NMe2)2 -2,6}(H2O)]2+ ÁV z Reference k2 (298 K) a À1 À1 (kg mol s ) (cm3 molÀ1) SOLVENT EXCHANGE ON METAL IONS 41 IV. Solvent Exchange on Lanthanides and Actinides A. TRIVALENT LANTHANIDES The trivalent lanthanide ions La3+, Ce3+, Pr3+, Nd3+, Pm3+, Sm3+, Eu3+, Gd3+, Tb3+, Dy3+, Ho3+, Er3+, Tm3+, Yb3+, and Lu3+, represent the most extended series of chemically similar metal ions and are denoted commonly as Ln3+.

FIG. 10. Possible mechanistic paths for water exchange on eight- and nine-coordinate lanthanides. predicted by this model: the a-activated mechanism for the small eightcoordinate ions, determined via the negative activation volumes, should be replaced by a d-activated mechanism for the larger nine-coordinate ions. This change in mechanism is supported by a computational study using classical molecular dynamics simulation. In recent years the subject of water exchange on lanthanide complexes attracted increasing attention owing to the use of Gd3+ as a contrast agent in medical magnetic resonance imaging (MRI).

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